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Details
Chinese Factory Supply Wholesale 1,3,5-BENZENETRIOL, 2-METHYL- 88-03-9 with Cheap Price
- Molecular Formula: C7H8 O3
- Molecular Weight: 140.139
- Vapor Pressure: 0.000276mmHg at 25°C
- Melting Point: 213-215 °C
- Boiling Point: 313.1°C at 760 mmHg
- PKA: 9.58±0.15(Predicted)
- Flash Point: 160.6°C
- PSA： 60.69000
- Density: 1.387g/cm3
- LogP: 1.11180
1,3,5-BENZENETRIOL, 2-METHYL-(Cas 88-03-9) Usage
InChI:InChI=1/C7H8O3/c1-4-6(9)2-5(8)3-7(4)10/h2-3,8-10H,1H3
88-03-9 Relevant articles
Discovery of Anti-TNBC Agents Targeting PTP1B: Total Synthesis, Structure-Activity Relationship, in Vitro and in Vivo Investigations of Jamunones
Hu, Caijuan,Li, Guoxun,Mu, Yu,Wu, Wenxi,Cao, Bixuan,Wang, Zixuan,Yu, Hainan,Guan, Peipei,Han, Li,Li, Liya,Huang, Xueshi
, p. 6008 - 6020 (2021/05/06)
Twenty-three natural jamunone analogues ...
Synthetic method of pilosin B and intermediate pseudomonophenols thereof
-
Paragraph 0034; 0067-0068, (2021/11/26)
The invention discloses a method for syn...
Biomimetic total syntheses of baefrutones A-D, baeckenon B, and frutescones A, D-F
Dong, Ying-Ying,Hou, Ji-Qin,Peng, Qiu-Shi,Wang, Hao,Yu, Jiang-Hong,Zhang, Bao-Bao,Zhao, Heng
, p. 1135 - 1139 (2020/02/22)
Biomimetic total syntheses of baefrutone...
ADDITIVE COMPOSITION FOR CULTURE MEDIUM, ADDITIVE COMPOUND FOR CULTURE MEDIUM, AND METHOD FOR CULTURE OF CELLS OR TISSUE USING SAME
-
Paragraph 0088, (2020/06/15)
The present invention provides a medium ...
88-03-9 Process route
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-
108-73-6
3,5-dihydroxyphenol
-
-
88-03-9
2,4,6-trihydroxytoluene
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
2
steps
1: POCl3
/ ethyl acetate / 0.5 h / 20 °C
2: sodium cyanoborohydride; methyl orange; hydrochloric acid / tetrahydrofuran / 12 h / 20 °C / pH 4.0
With
hydrogenchloride; methyl orange; sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; ethyl acetate;
1: Vilsmeier-Haack formylation;
|
|
|
Multi-step reaction
with
2
steps
1: 70 percent / POCl3
/ 20 °C
2: 60 percent / NaBH3
CN / tetrahydrofuran / 20 °C
With
sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran;
|
|
|
Multi-step reaction
with
2
steps
1: HCl; diethyl ether / Erwaermen des Reaktionsprodukts mit Wasser
2: acetic acid; ethanol; aqueous HCl / weiteres Reagens: amalgamiertes Zink
With
hydrogenchloride; diethyl ether; ethanol; acetic acid;
|
|
|
Multi-step reaction
with
2
steps
1: water; H2
SO4
2: zinc dust; NaOH-solution
With
sodium hydroxide; sulfuric acid; water; zinc;
|
|
|
Multi-step reaction
with
2
steps
1: water; H2
SO4
With
sulfuric acid; water;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / ethyl acetate / 2 h / 0 - 20 °C / Inert atmosphere
2: sodium cyanoborohydride / tetrahydrofuran / 0 - 20 °C
With
sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; ethyl acetate;
1: |Vilsmeier-Haack Formylation;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / ethyl acetate
2: methyl orange; sodium cyanoborohydride; hydrogenchloride / tetrahydrofuran; water / 12 h / 20 °C / pH 4
With
hydrogenchloride; methyl orange; sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; water; ethyl acetate;
1: |Vilsmeier-Haack Formylation;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / water; ethyl acetate / 1 h / 20 °C / Cooling with ice
2: zinc; hydrogenchloride / water; ethyl acetate; diethyl ether / 0.17 h / Cooling with ice
With
hydrogenchloride; zinc; trichlorophosphate;
In
diethyl ether; water; ethyl acetate;
1: |Vilsmeier-Haack Formylation / 2: |Clemmensen Reduction;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / 1,4-dioxane / 2 h / 20 °C / Cooling with ice
2: sodium cyanoborohydride; hydrogenchloride / tetrahydrofuran; water / 1 h / 20 °C
With
hydrogenchloride; sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; 1,4-dioxane; water;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / ethyl acetate / 20 °C
2: sodium cyanoborohydride; hydrogenchloride / water; tetrahydrofuran / 20 °C
With
hydrogenchloride; sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; water; ethyl acetate;
1: |Vilsmeier-Haack Formylation;
|
|
|
Multi-step reaction
with
2
steps
1: trichlorophosphate / acetonitrile / 2.5 h / 0 °C / Reflux
2: sodium cyanoborohydride; hydrogenchloride / water / 0 - 20 °C
With
hydrogenchloride; sodium cyanoborohydride; trichlorophosphate;
In
water; acetonitrile;
1: |Vilsmeier-Haack Formylation;
|
|
|
Multi-step reaction
with
2
steps
1.1: trichlorophosphate / 0.5 h / 0 - 25 °C
1.2: 3 h / 0 - 25 °C / Inert atmosphere
2.1: sodium cyanoborohydride; hydrogenchloride / tetrahydrofuran; water / 13 h / 0 - 20 °C
With
hydrogenchloride; sodium cyanoborohydride; trichlorophosphate;
In
tetrahydrofuran; water;
1.1: |Vilsmeier-Haack Formylation / 1.2: |Vilsmeier-Haack Formylation;
|
-
-
88-03-9
2,4,6-trihydroxytoluene
| Conditions | Yield |
|---|---|
|
With
potassium hydroxide; water;
at 150 - 160 ℃;
|
|
|
With
sodium hydroxide; zinc;
|
|
|
With
barium dihydroxide;
|
88-03-9 Upstream products
-
623-11-0
1-methyl-4-nitrosobenzene
-
118-96-7
2,4,6-Trinitrotoluene
-
487-70-7
2,4,6-trihydroxybenzaldehyde
-
95124-62-2
2,4,6-trihydroxy-3-methylbenzoic acid
88-03-9 Downstream products
-
6307-89-7
2,6-dihydroxy-4-methoxytoluene
-
39828-36-9
2-hydroxy-4,6-dimethoxytoluene
-
101268-53-5
1-(2,4,6-trihydroxy-3-methyl-phenyl)-hexan-1-one
-
131868-27-4
4-methyl-1-(2,4,6-trihydroxy-3-methyl-phenyl)-pentan-1-one
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